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Extra resources for Accelerate Your Keyboard Playing
It should be pointed out that in the cyanobacterium Synechocystis 6803 a specific mutation of the His-197 of D2 into Tyr re~~12~ in a loss of assembly (and, thus, of function) of the PS II complex ' . The 38 His-197 residue in D2 is in a homologous position to that of the M-subunit His that binds one of the bacteriochlorophylls of the special pair. This indicates that the His-197 residue in D2 has an important function in the PS II complex, even though it has not been proven that it contributes to the binding of P680.
Even though the non-heme iron does not appear to undergo redox changes during normal electron transport, there are conditions under which oxidation and/or subsequent rereduction can be detected in PS II. It was observed that a compound in the thylg~o~g could be oxidized by ' . The midpo~~t66edox ferricyanide and could rapidly oxidize Qk potential of this component was found to--be about 350-400 mV ' ,and this (at the time mysterious) component was dubbed Q400. Later, it was elegantly shown by EP~7and Mossbauer spectroscopy that Q400 was the non-heme iron near QA .
Deisenhofer and H. Michel, personal communication) favours a free lOa C=O. No informatjon is, at the present time, available for this group in Rb. sphaeroides. In p+ and BChl a+ spectra (Fig. 2), the highest frequency band in the C=O region could be in principle assigned to the 7c and/or lOa C=O ester groups. For bonds not involved in conjugation such as these ester carbonyls, only inductive coulombic effects from the n electron system would be expected (35). u. o!! I H2O W U Z «m a: 0 en m «
Accelerate Your Keyboard Playing by Dave Ddhlp 00320460 Limina